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かつては男子校で、現在は共学校の星華高校は未だに男子の数が多く、女子は肩身の狭い思いをしていた。そんな中、初の女性生徒会長になった鮎沢美咲は男子の横暴から女子を守るため日夜戦っていた。男勝りな美咲は男子を圧倒するが、苦しい家計を助けるため、メイド喫茶でアルバイトをしていた。ある日、その秘密を学校一のモテ男にして変人・碓氷拓海に知られてしまう。(Seika High School, once an all-boys school notorious for its wild students and for generally being a terrifying place for girls, has recently become a co-ed school. With the female population still a minority and living in fear of the over-the-top antics of the males, Misaki Ayuzawa takes it into her own hands to reform the school and allow the girls to feel safe in the rough environment.
Training, studying, and even becoming the first female student council president of the school, Misaki has gained a reputation among the male students body as an uptight, boy-hating dictator and as a shining hope for the teachers and fellow female students. However, despite her tough-as-nails appearance, she secretly works part-time at a maid café in order to support her family. Unfortunately, her hard-earned reputation is threatened when the popular, attractive, and somewhat impassive Takumi Usui takes an interest in her after discovering her in a maid uniform after school.)